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Toughening of vinyl ester resins by two-dimensional MXene nanosheets

Frontiers of Chemical Science and Engineering   Pages 1651-1658 doi: 10.1007/s11705-022-2208-5

Abstract: ester resin.ester resin and vinyl ester resin modified with MXene and M-MXene were investigated.The tensile and flexural strengths of the MXene-nanosheet-modified vinyl ester resin were 27.20% and25.32% higher, respectively, than those of the neat vinyl ester resin.ester resin being 52.57% and 54.60% higher, respectively, than those of the neat vinyl ester resin for

Keywords： MXene nanosheets     2D material     vinyl ester resin     modification     coupling agent    

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Insight of chemical environmental risk and its management from the vinyl chloride accident

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 4, doi: 10.1007/s11783-023-1652-x

Abstract: The combustion of vinyl chloride (VC) after the train derailment accident in Ohio, USA in February, 2023

Keywords： Vinyl chloride     Combustion     Chemical safety management     Environmental risk     Emerging contaminants    

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Uncovering the effect of poly(ethylene-co-vinyl alcohol) molecular weight and vinyl alcohol content on

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1484-1502 doi: 10.1007/s11705-023-2331-y

Abstract: Various hydrophilic poly(ethylene-co-vinyl alcohol) (EVOH) were used herein to precisely control theParticularly, to prepare pristine PSF and PSF/EVOH blends with increasing vinyl alcohol (VOH: 73%, 68%

Keywords： polysulfone     blend modification     ultrafiltration membrane     formation hydrodynamics     poly(ethylene-co-vinyl    

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Molecular diffusion in ternary poly(vinyl alcohol) solutions

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 6,   Pages 1003-1016 doi: 10.1007/s11705-021-2121-3

Abstract: The diffusion kinetics of a molecular probe—rhodamine B—in ternary aqueous solutions containing poly(vinylFor ternary poly(vinyl alcohol) solutions containing cationic or anionic surfactant, surfactant–polymer

Keywords： fluorescence correlation spectroscopy     poly(vinyl alcohol)     anomalous diffusion     crowding effects     dynamic    

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The prediction of adsorption isotherms of ester vapors on hypercrosslinked polymeric adsorbent

Liuyan WU,Lijuan JIA,Xiaohan LIU,Chao LONG

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 3,   Pages 482-490 doi: 10.1007/s11783-015-0826-6

Abstract: ethyl acetate, propyl acetate, isopropyl acetate and ethyl propionate on hypercrosslinked polymeric resinadsorption potential ( ) at three different temperatures all fell basically onto one single curve for every ester303K, and 333K, and also gave accurate predictive results for adsorption isotherms of the other two esterThe results proved the effectiveness of DA model for predicting the adsorption isotherms of ester compounds

Keywords： hypercrosslinked polymeric adsorbent     adsorption isotherm     ester     prediction    

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Reaction and characterization of crosslinking hyperbranched poly (amine-ester) with succine anhydride

XIAO Ling, WEI Xiuzhen, ZHU Baoku

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 4,   Pages 355-359 doi: 10.1007/s11705-007-0064-y

Abstract: Basing on hydroxyl terminated hyperbranched poly (amine-ester)s (HPAEs), the cross-linking reactionsand preparation of ester-crosslinked HPAE films were investigated using succine anhydride (SA) as crosslink

Keywords： different cross-linking     amine-ester     temperature     crosslinked     efficient    

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Control strategies for disinfection byproducts by ion exchange resin, nanofiltration and their sequential

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 10, doi: 10.1007/s11783-023-1725-x

Abstract:

● Effects of AER adsorption and NF on DBP precursors, DBPs, and TOX were examined.

Keywords： Disinfection byproducts     Control     Anion exchange resin     Nanofiltration     Cytotoxicity    

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Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts

Jinli ZHANG, Nan LIU, Wei LI, Bin DAI

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 4,   Pages 514-520 doi: 10.1007/s11705-011-1114-z

Abstract: Polyvinyl chloride is produced by polymerization of the vinyl chloride monomer (VCM), which is manufactured

Keywords： polyvinyl chloride     vinyl chloride monomer     acetylene hydrochlorination     non-mercury catalysts     green chemical    

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Removal of dissolved oxygen from water using a Pd-resin based catalytic reactor

Wenxin SHI, Chongwei CUI, Liye ZHAO, Shuili YU, Xia YUN

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 1,   Pages 107-111 doi: 10.1007/s11705-009-0154-0

Abstract: The removal of dissolved oxygen (DO) from water was studied experimentally in a Pd-resin base catalysteffects of various operating conditions, such as hydrogen and water flow rates, height of the catalytic resinIncreases of temperature, H gas rate and the height of the catalytic resin were helpful to improve the

Keywords： dissolved oxygen     palladium     catalytic reactor     hydrogen     resin    

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Impregnation of thermoplastic resin in jute fiber mat

LIU Xiaoye, DAI Gance

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 2,   Pages 145-149 doi: 10.1007/s11705-008-0030-3

Abstract: Impregnation rate of thermoplastic resin (polypropylene) in jute fiber mat and influence of relative

Keywords： polypropylene     diameter     influence     proportional     impregnation    

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Adsorption of 1,3-propanediol from synthetic mixture using polymeric resin as adsorbents

W. LUERRUK, A. SHOTIPRUK, V. TANTAYAKOM, P. PRASITCHOKE, C. MUANGNAPOH

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 1,   Pages 52-57 doi: 10.1007/s11705-009-0087-7

Abstract: adsorption capacity ( ) of 1,3-PDO at 160 g/L onto XAD-7 and XAD-16 was 835.96 and 584.61 mg 1,3-PDO/g dry resinThis result suggested that XAD-7 resin has a higher affinity for the 1,3-PDO adsorption than XAD-16 resinmixture at 50% ( / ) indicated that the desorption yield of 1,3-PDO from XAD-7 was lower than XAD-16 resinThis was due to the more favorable adsorption characteristics of XAD-7 resin than XAD-16 resin.

Keywords： adsorption     1     3-propanediol     glycerol     polymeric resin     adsorption isotherm    

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Comparison between two commercial uranium resins and a uranyl sulphate imprinted resin based on self-assembling

LIU Yaochi, XU Wei, XU Weijian, LIU Hanmao, ZHANG Xiaowen

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 4,   Pages 327-331 doi: 10.1007/s11705-007-0059-8

Abstract: self-assembling molecular imprinting technology and two kinds of commercial uranium resins (the medium pore resinD263 and strong base resin 201×7).The results show that the imprinted ion exchange resin has the fast kinetics, high adaptability toward

Keywords： saturation     molecular imprinting     imprinting technology     adaptability     commercial    

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Kinetics of UV curable alkyl 3-mercaptopropionate-vinyl silizane

SONG Jiale, CHEN Lixin, WANG Yazhou, CHEN Weiwei, WANG Rumin

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 4,   Pages 390-395 doi: 10.1007/s11705-008-0080-6

Abstract: Photopolymerization of vinyl-containing liquid silizane preceramic monomers copolymerized with thiolThe kinetics of alkyl 3-mercptopropionate-vinyl silizane under UV irradiation is investigated by usingThe experimental results show preliminarily that: (1) about 80% conversion of vinyl group has been achievedfunctionalities of the thiol group, the peak rate of copolymerization increases and the final conversion of the vinyltermination process; (4) the copolymerization is first-order, i.e., its rate is proportional to the vinyl

Keywords： step-growth     irradiation     bimolecular     preceramic     concentration photoinitiator    

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Performance of steel bridge deck pavement structure with ultra high performance concrete based on resin

Frontiers of Structural and Civil Engineering 2021, Volume 15, Issue 4,   Pages 895-904 doi: 10.1007/s11709-021-0759-z

Abstract: This research investigated a pavement system on steel bridge decks that use epoxy resin (EP) bonded ultra-highThe results show that the resin bonded UHPC pavement structure can reduce the weld strain in the steel

Keywords： steel bridge deck pavement     ultra-high-performance concrete     epoxy resin     composite structure     bending    

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Self-extinguishing and transparent epoxy resin modified by a phosphine oxide-containing bio-based derivative

Gang Tang, Ruiqing Zhao, Dan Deng, Yadong Yang, Depeng Chen, Bing Zhang, Xinliang Liu, Xiuyu Liu

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 5,   Pages 1269-1280 doi: 10.1007/s11705-021-2042-1

Abstract: A phosphine oxide-containing bio-based curing agent was synthesized by addition reaction between furan derivatives and diphenylphosphine oxide. The molecular structure of the as-prepared bio-based curing agent was confirmed by Fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy. Dynamic mechanical analysis results indicated that with the increase of bio-based curing agent content, the glass transition temperature of epoxy/bio-based curing agent composites decreased, which was related to the steric effect of diphenylphosphine oxide species that possibly hinder the curing reaction as well as the reduction in the cross-linking density by mono-functional N H. By the addition of 7.5 wt-% bio-based curing agent, the resulting epoxy composite achieved UL-94 V-0 rating, in addition to limiting oxygen index of 32.0 vol-%. With the increase of content for the bio-based curing agent, the peak of heat release rate and total heat release of the composites gradually decreased. The bio-based curing agent promoted the carbonization of the epoxy matrix, leading to higher char yield with good thermal resistance. The high-quality char layer served as an effective barrier to retard the diffusion of decomposition volatiles and oxygen between molten polymers and the flame. This study provides a renewable strategy for fabricating flame retardant and transparent epoxy thermoset.

Keywords： epoxy resin     flame retardant     furan derivative     diphenylphosphine oxide    

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Title Author Date Type Operation

Toughening of vinyl ester resins by two-dimensional MXene nanosheets

Journal Article

Insight of chemical environmental risk and its management from the vinyl chloride accident

Journal Article

Uncovering the effect of poly(ethylene-co-vinyl alcohol) molecular weight and vinyl alcohol content on

Journal Article

Molecular diffusion in ternary poly(vinyl alcohol) solutions

Journal Article

The prediction of adsorption isotherms of ester vapors on hypercrosslinked polymeric adsorbent

Liuyan WU,Lijuan JIA,Xiaohan LIU,Chao LONG

Journal Article

Reaction and characterization of crosslinking hyperbranched poly (amine-ester) with succine anhydride

XIAO Ling, WEI Xiuzhen, ZHU Baoku

Journal Article

Control strategies for disinfection byproducts by ion exchange resin, nanofiltration and their sequential

Journal Article

Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts

Jinli ZHANG, Nan LIU, Wei LI, Bin DAI

Journal Article

Removal of dissolved oxygen from water using a Pd-resin based catalytic reactor

Wenxin SHI, Chongwei CUI, Liye ZHAO, Shuili YU, Xia YUN

Journal Article

Impregnation of thermoplastic resin in jute fiber mat

LIU Xiaoye, DAI Gance

Journal Article

Adsorption of 1,3-propanediol from synthetic mixture using polymeric resin as adsorbents

W. LUERRUK, A. SHOTIPRUK, V. TANTAYAKOM, P. PRASITCHOKE, C. MUANGNAPOH

Journal Article

Comparison between two commercial uranium resins and a uranyl sulphate imprinted resin based on self-assembling

LIU Yaochi, XU Wei, XU Weijian, LIU Hanmao, ZHANG Xiaowen

Journal Article

Kinetics of UV curable alkyl 3-mercaptopropionate-vinyl silizane

SONG Jiale, CHEN Lixin, WANG Yazhou, CHEN Weiwei, WANG Rumin

Journal Article

Performance of steel bridge deck pavement structure with ultra high performance concrete based on resin

Journal Article

Self-extinguishing and transparent epoxy resin modified by a phosphine oxide-containing bio-based derivative

Gang Tang, Ruiqing Zhao, Dan Deng, Yadong Yang, Depeng Chen, Bing Zhang, Xinliang Liu, Xiuyu Liu

Journal Article